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Chemistry Practical WAEC EXAM 2026

tricks of calculating concentration



 In this post, I am going to show you how you can calculate the endpoint and concentration of acid in mole per dm3. so , if you are preparing to write WAEC 2026 chemistry practical exam, this post is for you. this year’s examination, you are going to titrate tetraoxosulphate (VI) acid and relative density(R.D) of the acid is given as 1.84 and its percent purity is 98% while volume of the acid to make up to 1000cm3 is 5.6cm3.

 Note:

R.D = 1.84

This means that for every  1cm3 of the acid contains 1.84g

So, 1000cm3 will be 1.84 x 1000 = 1840g

Now, we have the mass of the acid in 1000cm3  next:

 

Percentage Purity of the acid

98/100 x 1840  = 1803.2g of pure acid next

 

Concentration in mole of the acid

Mole = mass/molar mass

 

Mole = 1803.2/98 = 18.4 mole

Note : molar mass of H2SO4 is 98g/mole now , we can use dilution formula to find out the concentration in mole of the acid to be used in the titration.

                                              C1V1 = C2V2

C1   =  18.4mole

V1 = 5.6cm3

C2  = unknown

V2 = 1000cm3  then

                                              18.4 x5.6 =  1000 x C2 =

                                          C2 = 18.4 x 5.6/1000 = 0.103mol/dm3

Calculation of Endpoint of the Titration

Since the volume of pipette = 25  or 20 cm3 , we are using 25cm3

Concentration of NaOH in grams = 4g

The mole concentration  = 4/40  = 0.1mole per dm3

Mole concentration of the acid = 0.103mole per dm3

Volume of the acid  = Va unknown

      

                              CaVa/CbVb = a/b ( note : a and b = mole ratio of acid and base)

From the equation

H2SO4 + 2NaOH ----> Na2SO4  + 2H2O

So

                        0.103 x Va/ 0.1 x 25  =1/2

                        Va = 0.1 x 25x2/0.103    = 12.13cm3    

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