In this post, I am going to show you how you can calculate the endpoint and concentration of acid in mole per dm3. so , if you are preparing to write WAEC 2026 chemistry practical exam, this post is for you. this year’s examination, you are going to titrate tetraoxosulphate (VI) acid and relative density(R.D) of the acid is given as 1.84 and its percent purity is 98% while volume of the acid to make up to 1000cm3 is 5.6cm3.
Note:
R.D = 1.84
This means that for every 1cm3 of the acid contains 1.84g
So, 1000cm3 will be 1.84 x 1000 = 1840g
Now, we have the mass of the acid in 1000cm3 next:
Percentage Purity of the acid
98/100 x 1840 = 1803.2g of pure acid next
Concentration in mole of the acid
Mole = mass/molar mass
Mole = 1803.2/98 = 18.4 mole
Note : molar mass of H2SO4 is 98g/mole now , we can use dilution formula to find out the concentration in mole of the acid to be used in the titration.
C1V1 = C2V2
C1 = 18.4mole
V1 = 5.6cm3
C2 = unknown
V2 = 1000cm3 then
18.4 x5.6 = 1000 x C2 =
C2 = 18.4 x 5.6/1000 = 0.103mol/dm3
Calculation of Endpoint of the Titration
Since the volume of pipette = 25 or 20 cm3 , we are using 25cm3
Concentration of NaOH in grams = 4g
The mole concentration = 4/40 = 0.1mole per dm3
Mole concentration of the acid = 0.103mole per dm3
Volume of the acid = Va unknown
CaVa/CbVb = a/b ( note : a and b = mole ratio of acid and base)
From the equation
H2SO4 + 2NaOH ----> Na2SO4 + 2H2O
So
0.103 x Va/ 0.1 x 25 =1/2
Va = 0.1 x 25x2/0.103 = 12.13cm3
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